Up-converted white light emission in Er3+ doped MgAl2O4 nanocrystals

Abstract

This work presents the influence of host defect centers on the photoluminescence characteristics of Mg1 xErxAl2O4 (x = 0.005, 0.01, and 0.03) nanocrystals under UV and near-infrared (NIR) excitations. The spinel-structured nanocrystals are synthesized through the combus tion method. The Rietveld refinement and nuclear magnetic resonance analyses estimated the Er3þ ion occupancy at octahedral and other random sites of the MgAl2O4 lattice, and the existence of various lattice defects. Diffuse reflectance spectra showed broad bands attributed to oxygen vacancies as well as antisite defects and sharp peaks attributed to f–f transitions of Er3þ ions. The upconversion luminescence spectra consisted of sharp emission lines, ascribed to Er3þ ions, in the green and red wavelength regions, which overlapped over the broad curve attributed to intrinsic defects. Further, the UV excited downconversion luminescence spectra showed two broad emission bands in blue–violet and red-NIR regions with a very weak Er3þ ion emission feature. This up- and downconversion emission revealed energy trans fer between host and Er3þ ions via intrinsic defects. As a result, the emission color changes from bluish purple to white by varying the exci tation wavelength from UV to NIR. This rare earth activated luminescence from MgAl2O4 nanocrystals would exhibit potential applications in display devices and solid-state lighting.